微孔介孔Mg/Mn/ZN-MOF-74瑞禧材料
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微孔介孔Mg/Mn/ZN-MOF-74瑞禧材料
產(chǎn)品描述:
Driven by an energy crisis but consequently puzzled by various environmental problems, uranium, as the basic material of nuclear energy, is now receiving extensive attentions. In contrast to numerous sorbents applied in this field, metal-organic framework (MOFs), as a renovated material platform, has only recently been developed. How to improve the adsorption capacity of MOF materials towards UVIions, as well as taking advantage of the nature of these MOFs to design photo-switched behaviour for photo-triggered storage/release of UVIions are at present urgent problems and great challenges to be solved. Herein, we show a simple and facile method to target the goal. Through coordination-based post-synthetic strategy, microporous- mesoporous Zn-MOF-74 was easily functionalized by grafting coumarin on coordinatively unsaturated Zn(II) centers, yielding a series of coumarin-modified Zn-MOF-74 materials. The obtained samples displayed ultra-high adsorption capacity for UVIions from water at pH value of 4 with maximum adsorption capacities as high as 360mg/g
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